Fresh from defeat at the French Open, the Russian tennis pro will be hoping for better fortune this time around.
But the glamorous, successful Sharapova isn't the only tennis WAG with a career to match - or surpass - her man's.
Comparing the two earlier this year, he said: 'Actually, yes, I see big difference.
I mean, in the past I was saying that it's probably the best thing just that we are both from the same thing.
And although Kim's exact jacket is no longer up for grabs, you can nab a similar style with a click to the right from Asos or check out the edit below for our favourite alternatives from the likes of Zalando to Oasis.
When not supporting her other half, Mrs Murray focuses on her career as a pet portrait artist and spends her free time looking after the couple's beloved dogs Maggie May and Rusty at their home in Surrey.
Another tennis WAG who isn't afraid to share her opinions, Roger Federer's wife Mirka hit the headlines in November last year when she was caught heckling her husband's doubles partner Stanislas Wawrinka during a World Tour Finals match.